Bicarbonate Ion → Benzyl 6,7-dichloro-4H-1-benzopyran-4-carboxylate

HRID 93187Notes

Reaction equation

HRID 93187 reaction equation
[Br:16][CH2:17][c:18]1[cH:19][cH:20][cH:21][cH:22][cH:23]1.[C:24](=[O:25])([OH:26])[O-:27].[Cl:1][c:2]1[c:3]([Cl:15])[cH:4][c:5]2[c:6]([cH:14]1)[CH:7]([C:11](=[O:12])[OH:13])[CH:8]=[CH:9][O:10]2.[Cl:29][CH2:30][Cl:31].[Na+:28]>>[Cl:1][c:2]1[c:3]([Cl:15])[cH:4][c:5]2[c:6]([cH:14]1)[CH:7]([C:11](=[O:12])[O:13][CH2:17][c:18]1[cH:19][cH:20][cH:21][cH:22][cH:23]1)[CH:8]=[CH:9][O:10]2

Participants

6

Reactant 5

HCID 769Bicarbonate IonHCID 923Sodium ionHCID 6344DichloromethaneHCID 7498Benzyl BromideHCID 149865616,7-dichloro-4H-1-benzopyran-4-carboxylic acid

Product 1

HCID 19094451Benzyl 6,7-dichloro-4H-1-benzopyran-4-carboxylate

Sources & evidence

ORD record
ord-e5ffe38f25f84bbb9ed3db4c74ec27a6
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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