Potassium Cation → (5-Phenylethynyl-pyridin-3-yl)-carbamic acid tert-butyl ester

HRID 933388Notes

Reaction equation

HRID 933388 reaction equation
[Br:1][c:2]1[cH:3][n:4][cH:5][c:6]([C:8]#[C:9][c:10]2[cH:11][cH:12][cH:13][cH:14][cH:15]2)[cH:7]1.[C:16](=[O:17])([O-:18])[O-:19].[C:22]([CH3:23])([CH3:24])([CH3:25])[O:26][C:27]([NH2:28])=[O:29].[CH2:36]1[O:37][CH2:38][CH2:39][O:40][CH2:41]1.[CH3:30][NH:31][CH2:32][CH2:33][NH:34][CH3:35].[Cu:42][I:43].[K+:20].[K+:21]>>[c:2]1([NH:28][C:27]([O:26][C:22]([CH3:23])([CH3:24])[CH3:25])=[O:29])[cH:3][n:4][cH:5][c:6]([C:8]#[C:9][c:10]2[cH:11][cH:12][cH:13][cH:14][cH:15]2)[cH:7]1

Participants

8

Reactant 7

HCID 813Potassium Cation2×HCID 8070N,N'-DimethylethylenediamineHCID 19660Carbonate IonHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 312751,4-DioxaneHCID 77922tert-Butyl carbamateHCID 670476693-Bromo-5-phenylethynylpyridine

Product 1

HCID 49855802(5-Phenylethynyl-pyridin-3-yl)-carbamic acid tert-butyl ester

Sources & evidence

ORD record
ord-71d6d0c157394390a57cdf6e6f0aefd4
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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