Diethyl Ether → Bromide ion

HRID 933524Notes

Reaction equation

HRID 933524 reaction equation
[Br:1][CH:2]1[O:3][C:4](=[O:13])[c:5]2[cH:6][c:7]([O:11][CH3:12])[cH:8][cH:9][c:10]21.[CH2:33]([O:34][CH2:35][CH3:36])[CH3:37].[CH3:38][C:39]#[N:40].[c:14]1([P:20]([c:21]2[cH:22][cH:23][cH:24][cH:25][cH:26]2)[c:27]2[cH:28][cH:29][cH:30][cH:31][cH:32]2)[cH:15][cH:16][cH:17][cH:18][cH:19]1>>[Br-:1].[CH:2]1([P+:20]([c:14]2[cH:15][cH:16][cH:17][cH:18][cH:19]2)([c:21]2[cH:22][cH:23][cH:24][cH:25][cH:26]2)[c:27]2[cH:28][cH:29][cH:30][cH:31][cH:32]2)[O:3][C:4](=[O:13])[c:5]2[cH:6][c:7]([O:11][CH3:12])[cH:8][cH:9][c:10]21

Participants

6

Reactant 4

HCID 3283Diethyl EtherHCID 6342AcetonitrileHCID 11776TriphenylphosphineHCID 122985403-bromo-6-methoxyisobenzofuran-1(3H)-one

Product 2

HCID 259Bromide ionHCID 11562469(5-methoxy-3-oxo-1H-2-benzofuran-1-yl)-triphenylphosphanium

Sources & evidence

ORD record
ord-5a5b6b08a7a2415e919064d284f6a522
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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