Potassium Cation → 4-Benzylthio-2-oxo-2H-pyran

HRID 933756Notes

Reaction equation

HRID 933756 reaction equation
[CH2:9]([c:10]1[cH:11][cH:12][cH:13][cH:14][cH:15]1)[SH:16].[Cl:1][c:2]1[cH:3][c:4](=[O:8])[o:5][cH:6][cH:7]1.[K+:17].[K+:18].[O-:19][C:20]([O-:21])=[O:22].[O:23]=[CH:24][N:25]([CH3:26])[CH3:27]>>[c:2]1([S:16][CH2:9][c:10]2[cH:11][cH:12][cH:13][cH:14][cH:15]2)[cH:3][c:4](=[O:8])[o:5][cH:6][cH:7]1

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 6228DimethylformamideHCID 7509Benzyl mercaptanHCID 19660Carbonate IonHCID 109314664-Chloro-2H-pyran-2-one

Product 1

HCID 146427864-Benzylthio-2-oxo-2H-pyran

Sources & evidence

ORD record
ord-9ecafc118d3249649315bce0976a2b81
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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