Potassium Cation → HCID 59278472, compound

HRID 933848Notes

Reaction equation

HRID 933848 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([CH:8]([CH2:9][CH3:10])[OH:11])[cH:6][n:7]1.[C:42](=[O:43])([O-:44])[O-:45].[CH2:34]1[O:35][CH2:36][CH2:37][CH2:38]1.[CH3:12][C:13]([O:14][I:15]1([O:25][C:26]([CH3:27])=[O:28])([O:29][C:30]([CH3:31])=[O:32])[c:16]2[c:17]([cH:18][cH:19][cH:20][cH:21]2)[C:22](=[O:23])[O:24]1)=[O:33].[Cl:39][CH2:40][Cl:41].[K+:46].[K+:47].[O:48]=[Mn:49]=[O:50]>>[Br:1][c:2]1[cH:3][cH:4][c:5]([C:8]([CH2:9][CH3:10])=[O:11])[cH:6][n:7]1

Participants

8

Reactant 7

HCID 813Potassium Cation2×HCID 6344DichloromethaneHCID 8028TetrahydrofuranHCID 14801Manganese dioxideHCID 19660Carbonate IonHCID 159087TriacetoxyperiodinaneHCID 86640808HCID 86640808, compound

Product 1

HCID 59278472HCID 59278472, compound

Sources & evidence

ORD record
ord-80f7fa0281d749b5a484d8d51a507307
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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