Acetate → 3-(4-Formyl-3,5-dimethylphenyl)-acrylic acid methyl ester

HRID 934484Notes

Reaction equation

HRID 934484 reaction equation
[C:18]([CH:19]=[CH2:20])(=[O:21])[O:22][CH3:23].[CH3:16][OH:17].[N:12]([O-:13])=[O:14].[NH2:1][c:2]1[cH:3][c:4]([CH3:11])[c:5]([CH:6]=[O:7])[c:8]([CH3:10])[cH:9]1.[Na+:15].[O-:26][C:27]([CH3:28])=[O:29].[O-:30][C:31]([CH3:32])=[O:33].[OH2:24].[Pd+2:25]>>[c:2]1([CH:20]=[CH:19][C:18](=[O:21])[O:22][CH3:23])[cH:3][c:4]([CH3:11])[c:5]([CH:6]=[O:7])[c:8]([CH3:10])[cH:9]1

Participants

9

Reactant 8

HCID 175Acetate2×HCID 887MethanolHCID 923Sodium ionHCID 946NitriteHCID 962WaterHCID 7294Methyl AcrylateHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 123812354-Amino-2,6-dimethylbenzaldehyde

Product 1

HCID 866328203-(4-Formyl-3,5-dimethylphenyl)-acrylic acid methyl ester

Sources & evidence

ORD record
ord-5642a7c43a924ce1962d183154cb0ca1
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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