Sodium ion → Di-tert-butyl cyclopropane-1,2-dicarboxylate

HRID 937257Notes

Reaction equation

HRID 937257 reaction equation
[BH4-:1].[Br:3][C:4]1([C:14](=[O:15])[O:16][C:17]([CH3:18])([CH3:19])[CH3:20])[CH:5]([C:7](=[O:8])[O:9][C:10]([CH3:11])([CH3:12])[CH3:13])[CH2:6]1.[CH3:21][N:22]([CH3:23])[C:24](=[O:25])[CH3:26].[Co:33]([Cl:34])[Cl:35].[Na+:2].[OH2:27].[OH2:28].[OH2:29].[OH2:30].[OH2:31].[OH2:32]>>[CH:4]1([C:14](=[O:15])[O:16][C:17]([CH3:18])([CH3:19])[CH3:20])[CH:5]([C:7](=[O:8])[O:9][C:10]([CH3:11])([CH3:12])[CH3:13])[CH2:6]1

Participants

7

Reactant 6

HCID 923Sodium ionHCID 962Water6×HCID 24288Cobalt(II) chlorideHCID 28123BorohydrideHCID 31374DimethylacetamideHCID 23158974Di-tert-butyl 1-bromocyclopropane-1,2-dicarboxylate

Product 1

HCID 23158971Di-tert-butyl cyclopropane-1,2-dicarboxylate

Sources & evidence

ORD record
ord-c985c885235c43e78aa12a5e5d645b83
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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