Chloride → 6-bromo-4,4-dimethyl-3,4-dihydroquinolin-2(1H)-one

HRID 937376Notes

Reaction equation

HRID 937376 reaction equation
[Al+3:16].[Br:1][c:2]1[cH:3][cH:4][c:5]([NH:8][C:9]([CH:10]=[C:11]([CH3:12])[CH3:13])=[O:14])[cH:6][cH:7]1.[Cl-:15].[Cl-:17].[Cl-:18]>>[Br:1][c:2]1[cH:3][c:4]2[c:5]([cH:6][cH:7]1)[NH:8][C:9](=[O:14])[CH2:10][C:11]2([CH3:12])[CH3:13]

Participants

4

Reactant 3

HCID 312Chloride3×HCID 104727Aluminum CationHCID 5320952-Butenamide, N-(4-bromophenyl)-3-methyl-

Product 1

HCID 107295896-bromo-4,4-dimethyl-3,4-dihydroquinolin-2(1H)-one

Sources & evidence

ORD record
ord-574c683cff34441a8a6bcd5d1fae15cd
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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