HRID937703

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID175

Acetate

C2H3O2-

2 次

HCID813

Potassium cation

K+

3 次

HCID1061

Phosphate

O4P-3

HCID31275

1,4-Dioxane

C4H8O2

HCID66827

Boronic acid, phenyl-

C6H7BO2

HCID105144

Palladium(2+)

Pd+2

结构：c1ccc(-c2ccccc2P(C2CCCCC2)C2CCCCC2)cc1

HCID2734216

2-(Dicyclohexylphosphino)biphenyl

C24H31P

结构：CC(=O)OC1CC(n2cnc3c(Br)ncnc32)OC1CO[Si](C)(C)C(C)(C)C

HCID87293115

未命名化合物

PRODUCTS

生成物

结构：CC(=O)OC1CC(n2cnc3c(-c4ccccc4)ncnc32)OC1CO[Si](C)(C)C(C)(C)C

HCID67165417

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-177e603429f343c8937403a692e4baa7
来源数据集: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D
来源说明: Validation data from https://doi.org/10.1039/C8SC04228D

反应 SMILES

[C:43]([CH3:44])(=[O:45])[O:46][CH:47]1[CH:48]([CH2:62][O:63][Si:64]([CH3:65])([CH3:66])[C:67]([CH3:68])([CH3:69])[CH3:70])[O:49][CH:50]([n:52]2[c:53]3[n:54][cH:55][n:56][c:57]([Br:61])[c:58]3[n:59][cH:60]2)[CH2:51]1.[CH:1]1([P:2]([CH:3]2[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]2)[c:9]2[cH:10][cH:11][cH:12][cH:13][c:14]2-[c:15]2[cH:16][cH:17][cH:18][cH:19][cH:20]2)[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25]1.[K+:40].[K+:41].[K+:42].[O-:78][C:79]([CH3:80])=[O:81].[O-:82][C:83]([CH3:84])=[O:85].[O:71]1[CH2:72][CH2:73][O:74][CH2:75][CH2:76]1.[P:35]([O-:36])([O-:37])([O-:38])=[O:39].[Pd+2:77].[c:26]1([B:32]([OH:33])[OH:34])[cH:27][cH:28][cH:29][cH:30][cH:31]1>>[c:26]1(-[c:57]2[n:56][cH:55][n:54][c:53]3[n:52]([CH:50]4[O:49][CH:48]([CH2:62][O:63][Si:64]([CH3:65])([CH3:66])[C:67]([CH3:68])([CH3:69])[CH3:70])[CH:47]([O:46][C:43]([CH3:44])=[O:45])[CH2:51]4)[cH:60][n:59][c:58]32)[cH:27][cH:28][cH:29][cH:30][cH:31]1