Methanol → 5,6-Diamino-1,3-dihydrospiro[indene-2,3'-pyrrolo[2,3-b]pyridin]-2'(1'H)-one

HRID 938280Notes

Reaction equation

HRID 938280 reaction equation
[CH3:23][CH2:24][O:25][C:26]([CH3:27])=[O:28].[CH3:31][OH:32].[H:29][H:30].[NH2:1][c:2]1[cH:3][c:4]2[c:8]([cH:9][c:10]1[N+:11]([O-:12])=[O:13])[CH2:7][C:6]1([CH2:5]2)[C:14](=[O:22])[NH:15][c:16]2[n:17][cH:18][cH:19][cH:20][c:21]21>>[NH2:1][c:2]1[cH:3][c:4]2[c:8]([cH:9][c:10]1[NH2:11])[CH2:7][C:6]1([CH2:5]2)[C:14](=[O:22])[NH:15][c:16]2[n:17][cH:18][cH:19][cH:20][c:21]21

Participants

5

Reactant 4

HCID 887MethanolHCID 8857Ethyl AcetateHCID 595942805-amino-6-nitrospiro[1,3-dihydroindene-2,3'-1H-pyrrolo[2,3-b]pyridine]-2'-oneHCID 178418361HCID 178418361, compound

Product 1

HCID 595943005,6-Diamino-1,3-dihydrospiro[indene-2,3'-pyrrolo[2,3-b]pyridin]-2'(1'H)-one

Sources & evidence

ORD record
ord-37cb6033a426406ea66f804928434620
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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