HRID939130

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID962

Water

H2O

HCID8028

Tetrahydrofuran

C4H8O

结构：CC(C)(C)[Si](C)(C)Oc1ccc(C=O)c(O[Si](C)(C)C(C)(C)C)c1O[Si](C)(C)C(C)(C)C

HCID85996484

未命名化合物

HCID152764083

未命名化合物

HCID178418339

未命名化合物

PRODUCTS

生成物

结构：COc1cc(C=Cc2ccc(O[Si](C)(C)C(C)(C)C)c(O[Si](C)(C)C(C)(C)C)c2O[Si](C)(C)C(C)(C)C)cc(OC)c1OC

HCID69933473

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-5ccf737c537245c6a25eaca815d3d964
来源数据集: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D
来源说明: Validation data from https://doi.org/10.1039/C8SC04228D

反应 SMILES

[Br-:6].[C:21]([CH3:22])([CH3:23])([CH3:24])[Si:25]([O:26][c:27]1[c:28]([CH:29]=[O:30])[cH:31][cH:32][c:33]([O:43][Si:44]([CH3:45])([CH3:46])[C:47]([CH3:48])([CH3:49])[CH3:50])[c:34]1[O:35][Si:36]([CH3:37])([CH3:38])[C:39]([CH3:40])([CH3:41])[CH3:42])([CH3:51])[CH3:52].[CH2:1]([Li:2])[CH2:3][CH2:4][CH3:5].[CH2:54]1[O:55][CH2:56][CH2:57][CH2:58]1.[CH3:7][O:8][c:9]1[cH:10][c:11]([CH2:12][PH3+:13])[cH:14][c:15]([O:19][CH3:20])[c:16]1[O:17][CH3:18].[OH2:53]>>[CH3:7][O:8][c:9]1[cH:10][c:11]([CH:12]=[CH:29][c:28]2[c:27]([O:26][Si:25]([C:21]([CH3:22])([CH3:23])[CH3:24])([CH3:51])[CH3:52])[c:34]([O:35][Si:36]([CH3:37])([CH3:38])[C:39]([CH3:40])([CH3:41])[CH3:42])[c:33]([O:43][Si:44]([CH3:45])([CH3:46])[C:47]([CH3:48])([CH3:49])[CH3:50])[cH:32][cH:31]2)[cH:14][c:15]([O:19][CH3:20])[c:16]1[O:17][CH3:18]