Sodium ion → 4-chloro-6,7-dihydro-5H-cyclopenta[d]pyrimidine 1-oxide

HRID 940108Notes

Reaction equation

HRID 940108 reaction equation
[CH:35]([Cl:36])([Cl:37])[Cl:38].[Cl:11][c:12]1[cH:13][cH:14][cH:15][c:16]([C:17]([O:18][OH:20])=[O:19])[cH:21]1.[Cl:1][c:2]1[c:3]2[c:4]([n:5][cH:6][n:7]1)[CH2:8][CH2:9][CH2:10]2.[Na+:27].[Na+:28].[Na+:29].[Na+:30].[O-:31][C:32](=[O:33])[O-:34].[OH2:39].[S:22]([O-:23])([O-:24])(=[O:25])=[S:26]>>[Cl:1][c:2]1[c:3]2[c:4]([n+:5]([O-:19])[cH:6][n:7]1)[CH2:8][CH2:9][CH2:10]2

Participants

8

Reactant 7

HCID 923Sodium ion4×HCID 962WaterHCID 1084Thiosulfate ionHCID 6212ChloroformHCID 19660Carbonate IonHCID 70297m-Chloroperbenzoic acidHCID 133124494-chloro-5H,6H,7H-cyclopenta[d]pyrimidine

Product 1

HCID 142310914-chloro-6,7-dihydro-5H-cyclopenta[d]pyrimidine 1-oxide

Sources & evidence

ORD record
ord-0443668211324ce09e064a824f7bbebf
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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