Acetic Acid → 5,5,8,8-Tetramethyl-5,6,7,8-tetrahydronaphthalen-2-amine

HRID 940153Notes

Reaction equation

HRID 940153 reaction equation
[CH3:10][C:11]1([CH3:12])[c:13]2[c:14]([cH:15][cH:16][cH:17][cH:18]2)[C:19]([CH3:20])([CH3:21])[CH2:22][CH2:23]1.[CH3:24][C:25]1([CH3:40])[CH2:26][CH2:27][C:28]([CH3:38])([CH3:39])[c:29]2[cH:30][c:31]([N+:35]([O-:36])=[O:37])[cH:32][cH:33][c:34]21.[CH3:41][C:42](=[O:43])[OH:44].[Fe:45].[OH:1][N+:2](=[O:3])[O-:4].[S:5](=[O:6])(=[O:7])([OH:8])[OH:9]>>[CH3:24][C:25]1([CH3:40])[CH2:26][CH2:27][C:28]([CH3:38])([CH3:39])[c:29]2[cH:30][c:31]([NH2:35])[cH:32][cH:33][c:34]21

Participants

7

Reactant 6

HCID 176Acetic AcidHCID 944Nitric AcidHCID 1118Sulfuric AcidHCID 23925IronHCID 811861,1,4,4-TetramethyltetralinHCID 139871261,1,4,4-Tetramethyl-6-nitro-1,2,3,4-tetrahydronaphthalene

Product 1

HCID 114697605,5,8,8-Tetramethyl-5,6,7,8-tetrahydronaphthalen-2-amine

Sources & evidence

ORD record
ord-786e031e62564f9bbc8d1fdda4b8342a
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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