Acetate → Methyl 2-methanesulfonyl-5-methyl-4'-pentafluorosulfanylbiphenyl-4-carboxylate

HRID 940518Notes

Reaction equation

HRID 940518 reaction equation
[Br:19][c:20]1[cH:21][c:22]([CH3:34])[c:23]([C:24](=[O:25])[O:26][CH3:27])[cH:28][c:29]1[S:30](=[O:31])(=[O:32])[CH3:33].[Br:1][c:2]1[cH:3][cH:4][c:5]([S:8]([F:9])([F:10])([F:11])([F:12])[F:13])[cH:6][cH:7]1.[C:35](=[O:36])([O-:37])[O-:38].[CH3:15][C:16](=[O:17])[O-:18].[K+:14].[Na+:39].[Na+:40].[O:41]=[CH:42][N:43]([CH3:44])[CH3:45].[OH2:46]>>[c:2]1(-[c:20]2[cH:21][c:22]([CH3:34])[c:23]([C:24](=[O:25])[O:26][CH3:27])[cH:28][c:29]2[S:30](=[O:31])(=[O:32])[CH3:33])[cH:3][cH:4][c:5]([S:8]([F:9])([F:10])([F:11])([F:12])[F:13])[cH:6][cH:7]1

Participants

9

Reactant 8

HCID 175AcetateHCID 813Potassium CationHCID 923Sodium ion2×HCID 962WaterHCID 6228DimethylformamideHCID 19660Carbonate IonHCID 27791941-Bromo-4-(pentafluoro-lambda6-sulfanyl)benzeneHCID 10590825Methyl 4-bromo-5-methanesulfonyl-2-methylbenzoate

Product 1

HCID 59731052Methyl 2-methanesulfonyl-5-methyl-4'-pentafluorosulfanylbiphenyl-4-carboxylate

Sources & evidence

ORD record
ord-21ade7221d4e41f1a10b5261d4c92691
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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