Acetate → 1-(4-(Benzyloxy)-3-nitrophenyl)piperazine

HRID 941494Notes

Reaction equation

HRID 941494 reaction equation
[Br:1][c:2]1[cH:3][c:4]([N+:16](=[O:17])[O-:18])[c:5]([O:8][CH2:9][c:10]2[cH:11][cH:12][cH:13][cH:14][cH:15]2)[cH:6][cH:7]1.[C:25](=[O:26])([O-:27])[O-:28].[C:37]([O-:38])(=[O:39])[CH3:40].[C:42]([O-:43])(=[O:44])[CH3:45].[CH2:19]1[CH2:20][NH:21][CH2:22][CH2:23][NH:24]1.[Cs+:29].[Cs+:30].[O:31]1[CH2:32][CH2:33][O:34][CH2:35][CH2:36]1.[Pd+2:41]>>[c:2]1([N:21]2[CH2:20][CH2:19][NH:24][CH2:23][CH2:22]2)[cH:3][c:4]([N+:16](=[O:17])[O-:18])[c:5]([O:8][CH2:9][c:10]2[cH:11][cH:12][cH:13][cH:14][cH:15]2)[cH:6][cH:7]1

Participants

8

Reactant 7

HCID 175Acetate2×HCID 4837PiperazineHCID 19660Carbonate IonHCID 312751,4-DioxaneHCID 104967Cesium cation2×HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 112782421-(Benzyloxy)-4-bromo-2-nitrobenzene

Product 1

HCID 584256121-(4-(Benzyloxy)-3-nitrophenyl)piperazine

Sources & evidence

ORD record
ord-eb9b5784406448859f78263a05bcc1a3
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

Loading…