Bromide ion → Tert-butyl 3-bromo-5-formylbenzoate

HRID 942019Notes

Reaction equation

HRID 942019 reaction equation
[Br-:2].[Br:3][c:4]1[cH:5][c:6]([C:7](=[O:8])[O:9][C:10]([CH3:11])([CH3:12])[CH3:13])[cH:14][c:15]([CH2:17][OH:18])[cH:16]1.[C:34](=[O:35])([OH:36])[O-:37].[Cl:19][O-:20].[Cl:40][CH2:41][Cl:42].[K+:1].[Na+:21].[Na+:32].[Na+:33].[Na+:38].[OH2:22].[OH2:23].[OH2:24].[OH2:25].[OH2:26].[OH2:39].[S:27]([O-:28])([O-:29])(=[O:30])=[S:31]>>[Br:3][c:4]1[cH:5][c:6]([C:7](=[O:8])[O:9][C:10]([CH3:11])([CH3:12])[CH3:13])[cH:14][c:15]([CH:17]=[O:18])[cH:16]1

Participants

10

Reactant 9

HCID 259Bromide ionHCID 769Bicarbonate IonHCID 813Potassium CationHCID 923Sodium ion4×HCID 962Water6×HCID 1084Thiosulfate ionHCID 6344DichloromethaneHCID 61739HypochloriteHCID 58096191Tert-butyl 3-bromo-5-(hydroxymethyl)benzoate

Product 1

HCID 58095966Tert-butyl 3-bromo-5-formylbenzoate

Sources & evidence

ORD record
ord-79cc799ae5f6450eb07abca86ec2bff4
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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