Dichloromethane → 1-{[(2-Bromoethyl)oxy]methyl}-4-(1,1-dimethylethyl)benzene

HRID 943085Notes

Reaction equation

HRID 943085 reaction equation
[Al:46].[Br:1][N:2]1[C:3](=[O:4])[CH2:5][CH2:6][C:7]1=[O:8].[CH3:28][C:29]([CH3:30])([CH3:31])[c:32]1[cH:33][cH:34][c:35]([CH2:38][O:39][CH2:40][CH2:41][OH:42])[cH:36][cH:37]1.[Cl:43][CH2:44][Cl:45].[c:9]1([P:10]([c:11]2[cH:12][cH:13][cH:14][cH:15][cH:16]2)[c:17]2[cH:18][cH:19][cH:20][cH:21][cH:22]2)[cH:23][cH:24][cH:25][cH:26][cH:27]1>>[Br:1][CH2:41][CH2:40][O:39][CH2:38][c:35]1[cH:34][cH:33][c:32]([C:29]([CH3:28])([CH3:30])[CH3:31])[cH:37][cH:36]1

Participants

6

Reactant 5

HCID 6344DichloromethaneHCID 11776TriphenylphosphineHCID 67184N-bromobutanimideHCID 5359268AluminumHCID 104885912-({[4-(1,1-Dimethylethyl)phenyl]methyl}oxy)ethanol

Product 1

HCID 136543781-{[(2-Bromoethyl)oxy]methyl}-4-(1,1-dimethylethyl)benzene

Sources & evidence

ORD record
ord-890d018bc6114b8c8b7ee70be4d45f60
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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