Acetate → 5-Benzyl-2-methoxypyridine

HRID 945193Notes

Reaction equation

HRID 945193 reaction equation
[Br:9][c:10]1[cH:11][cH:12][c:13]([O:16][CH3:17])[n:14][cH:15]1.[C:44]([O-:45])(=[O:46])[CH3:47].[C:49]([O-:50])(=[O:51])[CH3:52].[CH2:18]([c:19]1[cH:20][cH:21][cH:22][cH:23][cH:24]1)[B:25]1[CH:26]2[CH2:27][CH2:28][CH2:29][CH:30]1[CH2:31][CH2:32][CH2:33]2.[CH2:34]1[O:35][CH2:36][CH2:37][CH2:38]1.[CH3:39][CH2:40][O:41][CH2:42][CH3:43].[K+:6].[K+:7].[K+:8].[P:1]([O-:2])([O-:3])([O-:4])=[O:5].[Pd+2:48]>>[c:10]1([CH2:18][c:19]2[cH:20][cH:21][cH:22][cH:23][cH:24]2)[cH:11][cH:12][c:13]([O:16][CH3:17])[n:14][cH:15]1

Participants

9

Reactant 8

HCID 175Acetate2×HCID 813Potassium Cation3×HCID 1061PhosphateHCID 3283Diethyl EtherHCID 8028TetrahydrofuranHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 27348955-Bromo-2-methoxypyridineHCID 41509249-Benzyl-9-borabicyclo(3.3.1)nonane

Product 1

HCID 584153415-Benzyl-2-methoxypyridine

Sources & evidence

ORD record
ord-57cd8b24c7ef47d299a4e3c2a3534356
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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