Chloride → 8-Methoxy-2-oxo-1,2,3,4-tetrahydroquinoline-5-carboxaldehyde

HRID 945501Notes

Reaction equation

HRID 945501 reaction equation
[CH3:14][O:15][CH:16]([Cl:17])[Cl:18].[CH3:1][O:2][c:3]1[cH:4][cH:5][cH:6][c:7]2[c:12]1[NH:11][C:10](=[O:13])[CH2:9][CH2:8]2.[Cl-:23].[Cl-:24].[Cl-:25].[Cl-:26].[Cl:20][CH2:21][Cl:22].[OH2:19].[Ti+4:27]>>[CH3:1][O:2][c:3]1[cH:4][cH:5][c:6]([CH:14]=[O:15])[c:7]2[c:12]1[NH:11][C:10](=[O:13])[CH2:9][CH2:8]2

Participants

7

Reactant 6

HCID 312Chloride4×HCID 962WaterHCID 6344DichloromethaneHCID 21004Methane, dichloromethoxy-HCID 114942Titanium cation (4+)HCID 133754763,4-Dihydro-8-methoxy-2(1H)-quinolinone

Product 1

HCID 859802658-Methoxy-2-oxo-1,2,3,4-tetrahydroquinoline-5-carboxaldehyde

Sources & evidence

ORD record
ord-b9afa39aba7d4cc3ad1dc5c94a83fa41
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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