Potassium Cation → 5-Hydroxy-7-isobutoxy-2,2-dimethyl-4-chromanone

HRID 948498Notes

Reaction equation

HRID 948498 reaction equation
[C:10](=[O:11])([O-:12])[O-:13].[CH2:18]([CH:19]([CH3:20])[CH3:21])[Br:22].[CH3:1][O:2][CH2:3][CH2:4][O:5][CH2:6][CH2:7][O:8][CH3:9].[I-:17].[K+:14].[K+:15].[K+:16].[OH:23][c:24]1[c:25]2[c:30]([cH:31][c:32]([OH:34])[cH:33]1)[O:29][C:28]([CH3:35])([CH3:36])[CH2:27][C:26]2=[O:37]>>[CH2:18]([CH:19]([CH3:20])[CH3:21])[O:34][c:32]1[cH:31][c:30]2[c:25]([c:24]([OH:23])[cH:33]1)[C:26](=[O:37])[CH2:27][C:28]([CH3:35])([CH3:36])[O:29]2

Participants

7

Reactant 6

HCID 813Potassium Cation3×HCID 65551-Bromo-2-methylpropaneHCID 8150DiglymeHCID 19660Carbonate IonHCID 30165Iodide IonHCID 8213625,7-Dihydroxy-2,2-dimethylchroman-4-one

Product 1

HCID 145929615-Hydroxy-7-isobutoxy-2,2-dimethyl-4-chromanone

Sources & evidence

ORD record
ord-cca19186a24e4d45ad96a00476e3c146
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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