Triphenylphosphine → Methyl 3-azidopyrrolidine-2-carboxylate

HRID 950805Notes

Reaction equation

HRID 950805 reaction equation
[CH3:1][O:2][C:3]([CH:4]1[NH:5][CH2:6][CH2:7][CH:8]1[OH:9])=[O:10].[O:11]=[C:12]([O:13][CH:14]([CH3:15])[CH3:16])[N:17]=[N:18][C:19]([O:20][CH:21]([CH3:22])[CH3:23])=[O:24].[c:25]1([P:26]([c:27]2[cH:28][cH:29][cH:30][cH:31][cH:32]2)[c:33]2[cH:34][cH:35][cH:36][cH:37][cH:38]2)[cH:39][cH:40][cH:41][cH:42][cH:43]1.[c:44]1([P:45]([c:46]2[cH:47][cH:48][cH:49][cH:50][cH:51]2)(=[O:52])[N:58]=[N+:59]=[N-:60])[cH:53][cH:54][cH:55][cH:56][cH:57]1>>[CH3:1][O:2][C:3]([CH:4]1[NH:5][CH2:6][CH2:7][CH:8]1[N:58]=[N+:59]=[N-:60])=[O:10]

Participants

5

Reactant 4

HCID 11776TriphenylphosphineHCID 75555Diisopropyl diazene-1,2-dicarboxylateHCID 199401P,P-Diphenylphosphinic azideHCID 22669281Methyl 3-hydroxypyrrolidine-2-carboxylate

Product 1

HCID 72234932Methyl 3-azidopyrrolidine-2-carboxylate

Sources & evidence

ORD record
ord-bf1946a4a72d4552966dcce1b5ad889f
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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