Potassium Cation → 2H-1-Benzopyran, 3-acetyl-7-methoxy-

HRID 950920Notes

Reaction equation

HRID 950920 reaction equation
[C:23](=[O:24])([O-:25])[O-:26].[CH3:31][N:32]([CH3:33])[CH:34]=[O:35].[K+:27].[K+:28].[Na+:30].[O:12]=[C:13]([CH:14]=[CH2:15])[CH3:16].[OH-:29].[OH:1][c:2]1[c:3]([CH:4]=[O:5])[cH:6][cH:7][c:8]([O:10][CH3:11])[cH:9]1.[cH:17]1[cH:18][cH:19][n:20][cH:21][cH:22]1>>[O:1]1[c:2]2[c:3]([cH:6][cH:7][c:8]([O:10][CH3:11])[cH:9]2)[CH:4]=[C:14]([C:13](=[O:12])[CH3:16])[CH2:15]1

Participants

9

Reactant 8

HCID 813Potassium Cation2×HCID 923Sodium ionHCID 961HydroxideHCID 1049PyridineHCID 6228DimethylformamideHCID 6570Methyl vinyl ketoneHCID 19660Carbonate IonHCID 696002-Hydroxy-4-Methoxybenzaldehyde

Product 1

HCID 424342H-1-Benzopyran, 3-acetyl-7-methoxy-

Sources & evidence

ORD record
ord-d3a10af4e4f04ea18607522d0d8b4a18
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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