Acetate → 3-(3-Acetylphenyl)pyridine

HRID 951732Notes

Reaction equation

HRID 951732 reaction equation
[C:1]([P:2]([C:3]([CH3:4])([CH3:5])[CH3:6])[c:7]1[cH:8][cH:9][cH:10][cH:11][c:12]1-[c:13]1[cH:14][cH:15][cH:16][cH:17][cH:18]1)([CH3:19])([CH3:20])[CH3:21].[C:22]([CH3:23])(=[O:24])[c:25]1[cH:26][c:27]([B:31]([OH:32])[OH:33])[cH:28][cH:29][cH:30]1.[C:43]([O-:44])(=[O:45])[CH3:46].[C:48]([O-:49])(=[O:50])[CH3:51].[CH2:52]1[O:53][CH2:54][CH2:55][CH2:56]1.[Cl:36][c:37]1[cH:38][n:39][cH:40][cH:41][cH:42]1.[F-:34].[K+:35].[Pd+2:47]>>[C:22]([CH3:23])(=[O:24])[c:25]1[cH:26][c:27](-[c:37]2[cH:38][n:39][cH:40][cH:41][cH:42]2)[cH:28][cH:29][cH:30]1

Participants

9

Reactant 8

HCID 175Acetate2×HCID 813Potassium CationHCID 8028TetrahydrofuranHCID 122873-ChloropyridineHCID 28179Fluoride IonHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 27342152-(Di-tert-butylphosphino)biphenylHCID 27343103-Acetylphenylboronic acid

Product 1

HCID 120407253-(3-Acetylphenyl)pyridine

Sources & evidence

ORD record
ord-3c473ab6a77d45dabdff02fd0e6f431f
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

Loading…