Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI) → 4-(3-[1,3]Dioxan-2-ylphenyl)-1,1,1-trifluoro-4-methylpentan-2-one

HRID 952635Notes

Reaction equation

HRID 952635 reaction equation
[Br:1][c:2]1[cH:3][c:4]([CH:8]2[O:9][CH2:10][CH2:11][CH2:12][O:13]2)[cH:5][cH:6][cH:7]1.[Cu:24][I:25].[F:14][C:15]([C:16]([CH:17]=[C:18]([CH3:19])[CH3:20])=[O:21])([F:22])[F:23]>>[c:2]1([C:18]([CH2:17][C:16]([C:15]([F:14])([F:22])[F:23])=[O:21])([CH3:19])[CH3:20])[cH:3][c:4]([CH:8]2[O:9][CH2:10][CH2:11][CH2:12][O:13]2)[cH:5][cH:6][cH:7]1

Participants

4

Reactant 3

HCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 101058152-(3-Bromophenyl)-1,3-dioxaneHCID 220326911,1,1-Trifluoro-4-methylpent-3-en-2-one

Product 1

HCID 578099664-(3-[1,3]Dioxan-2-ylphenyl)-1,1,1-trifluoro-4-methylpentan-2-one

Sources & evidence

ORD record
ord-bd9c41c7ae634399918aafc7ceff3eaf
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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