Potassium Cation → Diethyl 5-oxoazepane-1,4-dicarboxylate

HRID 952707Notes

Reaction equation

HRID 952707 reaction equation
[C:21](=[O:22])([O-:23])[O-:24].[C:9](=[O:10])([O:11][CH2:12][CH3:13])[N:14]1[CH2:15][CH2:16][C:17](=[O:20])[CH2:18][CH2:19]1.[CH2:27]([O:28][CH2:29][CH3:30])[CH3:31].[K+:25].[K+:26].[N+:1](=[N-:2])=[CH:3][C:4](=[O:5])[O:6][CH2:7][CH3:8]>>[CH:3]1([C:4](=[O:5])[O:6][CH2:7][CH3:8])[C:17](=[O:20])[CH2:16][CH2:15][N:14]([C:9](=[O:10])[O:11][CH2:12][CH3:13])[CH2:19][CH2:18]1

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 3283Diethyl EtherHCID 12192Ethyl diazoacetateHCID 19660Carbonate IonHCID 34767Ethyl 4-oxo-1-piperidinecarboxylate

Product 1

HCID 12485293Diethyl 5-oxoazepane-1,4-dicarboxylate

Sources & evidence

ORD record
ord-1782892341674188893c2f1659b4d2dd
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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