HRID952970

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID1118

Sulfuric acid

H2O4S

HCID8028

Tetrahydrofuran

C4H8O

HCID12679

Hexamethylphosphoramide

C6H18N3OP

HCID554053

Pentanoic acid, 5-oxo-, methyl ester

C6H10O3

HCID4182722

未命名化合物

HCID19017785

未命名化合物

HCID178418339

未命名化合物

PRODUCTS

生成物

HCID53662957

Methyl 8-hydroxyoct-5-enoate

C9H16O3

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-9caded10f411461596c4ef6c5d08250d
来源数据集: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D
来源说明: Validation data from https://doi.org/10.1039/C8SC04228D

反应 SMILES

[Br-:12].[CH2:36]([Li:37])[CH2:38][CH2:39][CH3:40].[CH3:1][O:2][C:3]([O:4][C:5]([O:6][CH3:7])([CH3:8])[CH3:9])([CH3:10])[CH3:11].[CH3:60][N:61]([CH3:62])[P:63](=[O:64])([N:65]([CH3:66])[CH3:67])[N:68]([CH3:69])[CH3:70].[CH:41](=[O:42])[CH2:43][CH2:44][CH2:45][C:46](=[O:47])[O:48][CH3:49].[O:55]1[CH2:56][CH2:57][CH2:58][CH2:59]1.[OH:13][CH2:14][CH2:15][CH2:16][P+:17]([c:18]1[cH:19][cH:20][cH:21][cH:22][cH:23]1)([c:24]1[cH:25][cH:26][cH:27][cH:28][cH:29]1)[c:30]1[cH:31][cH:32][cH:33][cH:34][cH:35]1.[S:50](=[O:51])(=[O:52])([OH:53])[OH:54]>>[OH:13][CH2:14][CH2:15][CH:16]=[CH:41][CH2:43][CH2:44][CH2:45][C:46](=[O:47])[O:48][CH3:49]