Sodium ion → tert-Butyl-[4-(4-chloro-phenyl)-4-methoxy-butoxy]-diphenyl-silane

HRID 953240Notes

Reaction equation

HRID 953240 reaction equation
[C:3]([CH3:4])([CH3:5])([CH3:6])[Si:7]([O:8][CH2:9][CH2:10][CH2:11][CH:12]([OH:13])[c:14]1[cH:15][cH:16][c:17]([Cl:20])[cH:18][cH:19]1)([c:21]1[cH:22][cH:23][cH:24][cH:25][cH:26]1)[c:27]1[cH:28][cH:29][cH:30][cH:31][cH:32]1.[CH2:35]1[O:36][CH2:37][CH2:38][CH2:39]1.[CH3:33][I:34].[H-:2].[Na+:1]>>[C:3]([CH3:4])([CH3:5])([CH3:6])[Si:7]([O:8][CH2:9][CH2:10][CH2:11][CH:12]([O:13][CH3:33])[c:14]1[cH:15][cH:16][c:17]([Cl:20])[cH:18][cH:19]1)([c:21]1[cH:22][cH:23][cH:24][cH:25][cH:26]1)[c:27]1[cH:28][cH:29][cH:30][cH:31][cH:32]1

Participants

6

Reactant 5

HCID 923Sodium ionHCID 6328Methyl iodideHCID 8028TetrahydrofuranHCID 166653HydrideHCID 595688264-(tert-Butyl-diphenyl-silanyloxy)-1-(4-chloro-phenyl)-butan-1-ol

Product 1

HCID 59568823tert-Butyl-[4-(4-chloro-phenyl)-4-methoxy-butoxy]-diphenyl-silane

Sources & evidence

ORD record
ord-b0f8bbaf01af45d39441f09e6c731c22
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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