HRID953369

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6210

3,5-Dimethylpyrazole

C5H8N2

HCID14915

Chromium trioxide

CrO3

结构：CC(CCC(O[SiH](C)C)C(C)(C)C)C1CCC2C3CC=C4CC(OC5CCCCO5)CCC4(C)C3CCC12C

HCID178447677

未命名化合物

PRODUCTS

生成物

结构：CC(CCC(O[SiH](C)C)C(C)(C)C)C1CCC2C3C(=O)C=C4CC(OC5CCCCO5)CCC4(C)C3CCC12C

HCID178447678

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-c0580cb526f94ecda965fd63d6fc7f1f
来源数据集: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D
来源说明: Validation data from https://doi.org/10.1039/C8SC04228D

反应 SMILES

[C:12]([CH3:13])([CH3:14])([CH3:15])[CH:16]([CH2:17][CH2:18][CH:19]([CH3:20])[CH:21]1[CH2:22][CH2:23][CH:24]2[CH:25]3[CH2:26][CH:27]=[C:28]4[CH2:29][CH:30]([O:40][CH:41]5[O:42][CH2:43][CH2:44][CH2:45][CH2:46]5)[CH2:31][CH2:32][C:33]4([CH3:34])[CH:35]3[CH2:36][CH2:37][C:38]12[CH3:39])[O:47][SiH:48]([CH3:49])[CH3:50].[CH3:5][c:6]1[cH:7][c:8]([CH3:9])[nH:10][n:11]1.[O:1]=[Cr:2](=[O:3])=[O:4]>>[O:1]=[C:26]1[CH:25]2[CH:24]3[CH2:23][CH2:22][CH:21]([CH:19]([CH2:18][CH2:17][CH:16]([C:12]([CH3:13])([CH3:14])[CH3:15])[O:47][SiH:48]([CH3:49])[CH3:50])[CH3:20])[C:38]3([CH3:39])[CH2:37][CH2:36][CH:35]2[C:33]2([CH3:34])[C:28](=[CH:27]1)[CH2:29][CH:30]([O:40][CH:41]1[O:42][CH2:43][CH2:44][CH2:45][CH2:46]1)[CH2:31][CH2:32]2