Potassium Cation → Ethyl 1-(4-nitrophenyl)piperidine-4-carboxylate

HRID 953459Notes

Reaction equation

HRID 953459 reaction equation
[C:22](=[O:23])([O-:24])[O-:25].[CH2:11]([CH3:12])[O:13][C:14](=[O:15])[CH:16]1[CH2:17][CH2:18][NH:19][CH2:20][CH2:21]1.[CH3:28][C:29]#[N:30].[F:1][c:2]1[cH:3][cH:4][c:5]([N+:8](=[O:9])[O-:10])[cH:6][cH:7]1.[K+:26].[K+:27]>>[c:2]1([N:19]2[CH2:18][CH2:17][CH:16]([C:14]([O:13][CH2:11][CH3:12])=[O:15])[CH2:21][CH2:20]2)[cH:3][cH:4][c:5]([N+:8](=[O:9])[O-:10])[cH:6][cH:7]1

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 6342AcetonitrileHCID 9590p-FluoronitrobenzeneHCID 19660Carbonate IonHCID 70770Ethyl 4-piperidinecarboxylate

Product 1

HCID 2796870Ethyl 1-(4-nitrophenyl)piperidine-4-carboxylate

Sources & evidence

ORD record
ord-52382514462542e4bb0b189b91735250
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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