Potassium Cation → 6-Ethynyl-1-(iso-propyl-methyl-amino)-4,4-dimethyl-1,2,3,4-tetrahydronaphthalene

HRID 953827Notes

Reaction equation

HRID 953827 reaction equation
[C:26](=[O:27])([O-:28])[O-:29].[CH3:1][N:2]([CH:3]1[CH2:4][CH2:5][C:6]([CH3:19])([CH3:20])[c:7]2[cH:8][c:9]([C:13]#[C:14][Si:15]([CH3:16])([CH3:17])[CH3:18])[cH:10][cH:11][c:12]21)[CH:21]([CH3:22])[CH3:23].[CH3:24][OH:25].[CH3:32][CH2:33][O:34][C:35](=[O:36])[CH3:37].[K+:30].[K+:31]>>[CH3:1][N:2]([CH:3]1[CH2:4][CH2:5][C:6]([CH3:19])([CH3:20])[c:7]2[cH:8][c:9]([C:13]#[CH:14])[cH:10][cH:11][c:12]21)[CH:21]([CH3:22])[CH3:23]

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 887MethanolHCID 8857Ethyl AcetateHCID 19660Carbonate IonHCID 225688201-(Methyl-iso-propylamino)-4,4-dimethyl-6-trimethylsilanylethynyl-1,2,3,4-tetrahydro-naphthalene

Product 1

HCID 225689626-Ethynyl-1-(iso-propyl-methyl-amino)-4,4-dimethyl-1,2,3,4-tetrahydronaphthalene

Sources & evidence

ORD record
ord-329edbe066df434791a50e53d2322037
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

Loading…