Bromide ion → Ethyl 2-ethyl-4-methylenecyclopentanecarboxylate

HRID 954108Notes

Reaction equation

HRID 954108 reaction equation
[Br-:19].[CH2:14]1[O:15][CH2:16][CH2:17][CH2:18]1.[CH2:1]([CH3:2])[CH:3]1[CH:4]([C:9](=[O:10])[O:11][CH2:12][CH3:13])[CH2:5][C:6](=[O:8])[CH2:7]1.[CH3:20][P+:21]([c:22]1[cH:23][cH:24][cH:25][cH:26][cH:27]1)([c:28]1[cH:29][cH:30][cH:31][cH:32][cH:33]1)[c:34]1[cH:35][cH:36][cH:37][cH:38][cH:39]1>>[CH2:1]([CH3:2])[CH:3]1[CH:4]([C:9](=[O:10])[O:11][CH2:12][CH3:13])[CH2:5][C:6](=[CH2:14])[CH2:7]1

Participants

5

Reactant 4

HCID 259Bromide ionHCID 8028TetrahydrofuranHCID 74506TriphenylmethylphosphoniumHCID 58010012Cyclopentanecarboxylic acid, 2-ethyl-4-oxo-, ethyl ester

Product 1

HCID 58558026Ethyl 2-ethyl-4-methylenecyclopentanecarboxylate

Sources & evidence

ORD record
ord-95f9e603553b4913817c7fed844ddc20
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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