HRID954160

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID176

Acetic Acid

C2H4O2

HCID923

Sodium ion

Na+

HCID962

Water

H2O

HCID7498

alpha-Bromotoluene

C7H7Br

HCID123061

1-(Bromomethyl)-3-(trifluoromethyl)benzene

C8H6BrF3

HCID166653

Hydride

H-

HCID567352

1,4-Dioxaspiro[4.5]decan-8-ol

C8H14O3

HCID11139485

8-(benzyloxy)-1,4-dioxaspiro[4.5]decane

C15H20O3

PRODUCTS

生成物

HCID10987369

4-(Benzyloxy)cyclohexanone

C13H16O2

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-64dbc0e56644420489ad42bf2f03b1f0
来源数据集: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D
来源说明: Validation data from https://doi.org/10.1039/C8SC04228D

反应 SMILES

[CH3:53][C:54](=[O:55])[OH:56].[F:22][C:23]([F:24])([F:25])[c:26]1[cH:27][c:28]([CH2:29][Br:30])[cH:31][cH:32][cH:33]1.[H-:12].[Na+:13].[O:1]1[C:2]2([CH2:3][CH2:4][CH:5]([OH:6])[CH2:7][CH2:8]2)[O:9][CH2:10][CH2:11]1.[OH2:52].[c:14]1([CH2:15][Br:16])[cH:17][cH:18][cH:19][cH:20][cH:21]1.[c:34]1([CH2:40][O:41][CH:42]2[CH2:43][CH2:44][C:45]3([O:46][CH2:49][CH2:48][O:47]3)[CH2:50][CH2:51]2)[cH:35][cH:36][cH:37][cH:38][cH:39]1>>[c:34]1([CH2:40][O:41][CH:42]2[CH2:43][CH2:44][C:45](=[O:46])[CH2:50][CH2:51]2)[cH:35][cH:36][cH:37][cH:38][cH:39]1