Potassium Cation → 4-Bromo-2-(3-oxopentan-2-yloxy)anisole

HRID 955321Notes

Reaction equation

HRID 955321 reaction equation
[Br:11][CH:12]([CH3:13])[C:14]([CH2:15][CH3:16])=[O:17].[Br:1][c:2]1[cH:3][cH:4][c:5]([O:9][CH3:10])[c:6]([OH:8])[cH:7]1.[C:18](=[O:19])([O-:20])[O-:21].[K+:22].[K+:23].[O:24]=[CH:25][N:26]([CH3:27])[CH3:28].[OH2:29]>>[Br:1][c:2]1[cH:3][cH:4][c:5]([O:9][CH3:10])[c:6]([O:8][CH:12]([CH3:13])[C:14]([CH2:15][CH3:16])=[O:17])[cH:7]1

Participants

7

Reactant 6

HCID 813Potassium Cation2×HCID 962WaterHCID 6228DimethylformamideHCID 19660Carbonate IonHCID 1422285-Bromo-2-methoxyphenolHCID 5450922-Bromo-3-pentanone

Product 1

HCID 227341244-Bromo-2-(3-oxopentan-2-yloxy)anisole

Sources & evidence

ORD record
ord-25c55ebaa4d647e19e08b9d9800d95b7
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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