Potassium Cation → Diethyl 5-(1-cyanocyclopentyl)benzene-1,3-dioate

HRID 956547Notes

Reaction equation

HRID 956547 reaction equation
[Br:30][CH2:31][CH2:32][CH2:33][CH2:34][Br:35].[C:1](#[N:2])[CH2:3][c:4]1[cH:5][c:6]([C:15](=[O:16])[O:17][CH2:18][CH3:19])[cH:7][c:8]([C:10](=[O:11])[O:12][CH2:13][CH3:14])[cH:9]1.[CH2:36]1[O:37][CH2:38][CH2:39][CH2:40]1.[CH3:20][Si:21]([N-:22][Si:23]([CH3:24])([CH3:25])[CH3:26])([CH3:27])[CH3:28].[K+:29]>>[C:1](#[N:2])[C:3]1([c:4]2[cH:5][c:6]([C:15](=[O:16])[O:17][CH2:18][CH3:19])[cH:7][c:8]([C:10](=[O:11])[O:12][CH2:13][CH3:14])[cH:9]2)[CH2:31][CH2:32][CH2:33][CH2:34]1

Participants

6

Reactant 5

HCID 813Potassium CationHCID 8028TetrahydrofuranHCID 80561,4-DibromobutaneHCID 3280088Npc316347HCID 59709094Diethyl 5-(cyanomethyl)benzene-1,3-dioate

Product 1

HCID 67318465Diethyl 5-(1-cyanocyclopentyl)benzene-1,3-dioate

Sources & evidence

ORD record
ord-a780cfb2de2b448cb9629a25c5a9dee7
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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