Acetate → Methyl 4-benzo[b]thien-2-ylbenzoate

HRID 958121Notes

Reaction equation

HRID 958121 reaction equation
[Br-:30].[Br:1][c:2]1[cH:3][cH:4][c:5]([C:6](=[O:7])[O:8][CH3:9])[cH:10][cH:11]1.[C:24](=[O:25])([O-:26])[O-:27].[C:48]([O-:49])(=[O:50])[CH3:51].[C:53]([O-:54])(=[O:55])[CH3:56].[CH3:31][CH2:32][CH2:33][CH2:34][N+:35]([CH2:36][CH2:37][CH2:38][CH3:39])([CH2:40][CH2:41][CH2:42][CH3:43])[CH2:44][CH2:45][CH2:46][CH3:47].[K+:28].[K+:29].[OH2:57].[Pd+2:52].[s:12]1[c:13]2[c:14]([cH:15][c:16]1[B:17]([OH:18])[OH:19])[cH:20][cH:21][cH:22][cH:23]2>>[c:2]1(-[c:16]2[s:12][c:13]3[c:14]([cH:15]2)[cH:20][cH:21][cH:22][cH:23]3)[cH:3][cH:4][c:5]([C:6](=[O:7])[O:8][CH3:9])[cH:10][cH:11]1

Participants

10

Reactant 9

HCID 175Acetate2×HCID 259Bromide ionHCID 813Potassium Cation2×HCID 962WaterHCID 2359Benzo(B)Thiophene-2-Boronic AcidHCID 12081Methyl 4-bromobenzoateHCID 16028TetrabutylammoniumHCID 19660Carbonate IonHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

Product 1

HCID 4137384Methyl 4-benzo[b]thien-2-ylbenzoate

Sources & evidence

ORD record
ord-7fe8725f9f5841fcbe13fdd8e2c03b36
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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