Ethanol → Ethyl 3-ethynyl-6-nitro-1-benzothiophene-2-carboxylate

HRID 959015Notes

Reaction equation

HRID 959015 reaction equation
[C:24](=[O:25])([O-:26])[O-:27].[CH2:33]1[O:34][CH2:35][CH2:36][CH2:37]1.[CH3:30][CH2:31][OH:32].[K+:28].[K+:29].[N+:1](=[O:2])([O-:3])[c:4]1[cH:5][c:6]2[c:7]([c:8]([C:16]#[C:17][Si:18]([CH3:19])([CH3:20])[CH3:21])[c:9]([C:11](=[O:12])[O:13][CH2:14][CH3:15])[s:10]2)[cH:22][cH:23]1>>[N+:1](=[O:2])([O-:3])[c:4]1[cH:5][c:6]2[c:7]([c:8]([C:16]#[CH:17])[c:9]([C:11](=[O:12])[O:13][CH2:14][CH3:15])[s:10]2)[cH:22][cH:23]1

Participants

6

Reactant 5

HCID 702EthanolHCID 813Potassium Cation2×HCID 8028TetrahydrofuranHCID 19660Carbonate IonHCID 67549085Ethyl 6-nitro-3-[(trimethylsilyl)ethynyl]-1-benzothiophene-2-carboxylate

Product 1

HCID 86648747Ethyl 3-ethynyl-6-nitro-1-benzothiophene-2-carboxylate

Sources & evidence

ORD record
ord-3d9084e570fe47d5a63eb4e7d5c5b65c
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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