Cholestanol → Cholestan-3-one

HRID 960627Notes

Reaction equation

HRID 960627 reaction equation
[Ag+:34].[Ag+:35].[Ag+:36].[Ag+:37].[CH3:38][CH2:39][O:40][C:41](=[O:42])[CH3:43].[OH:1][CH:2]1[CH2:3][CH:4]2[CH2:5][CH2:6][CH:7]3[CH:8]4[CH2:9][CH2:10][CH:11]([CH:12]([CH2:13][CH2:14][CH2:15][CH:16]([CH3:17])[CH3:18])[CH3:19])[C:20]4([CH3:28])[CH2:21][CH2:22][CH:23]3[C:24]2([CH3:27])[CH2:25][CH2:26]1.[Si:29]([O-:30])([O-:31])([O-:32])[O-:33]>>[O:1]=[C:2]1[CH2:3][CH:4]2[CH2:5][CH2:6][CH:7]3[CH:8]4[CH2:9][CH2:10][CH:11]([CH:12]([CH2:13][CH2:14][CH2:15][CH:16]([CH3:17])[CH3:18])[CH3:19])[C:20]4([CH3:28])[CH2:21][CH2:22][CH:23]3[C:24]2([CH3:27])[CH2:25][CH2:26]1

Participants

5

Reactant 4

HCID 3240CholestanolHCID 8857Ethyl AcetateHCID 104755Silver cation4×HCID 104812Silicate

Product 1

HCID 85881Cholestan-3-one

Sources & evidence

ORD record
ord-442f9e3cefca4ce58f442cd3a19f403c
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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