Sodium ion → t-butyl N-[2-nitro-5-(2-pyrrolidinophenoxy)phenyl]-N-methylcarbamate

HRID 961902Notes

Reaction equation

HRID 961902 reaction equation
[CH3:34][N:35]([CH3:36])[CH:37]=[O:38].[Cl:13][c:14]1[cH:15][cH:16][c:17]([N+:29](=[O:30])[O-:31])[c:18]([N:20]([C:21]([O:22][C:23]([CH3:24])([CH3:25])[CH3:26])=[O:27])[CH3:28])[cH:19]1.[H-:32].[N:1]1([c:6]2[c:7]([OH:12])[cH:8][cH:9][cH:10][cH:11]2)[CH2:2][CH2:3][CH2:4][CH2:5]1.[Na+:33]>>[N:1]1([c:6]2[c:7]([O:12][c:14]3[cH:15][cH:16][c:17]([N+:29](=[O:30])[O-:31])[c:18]([N:20]([C:21]([O:22][C:23]([CH3:24])([CH3:25])[CH3:26])=[O:27])[CH3:28])[cH:19]3)[cH:8][cH:9][cH:10][cH:11]2)[CH2:2][CH2:3][CH2:4][CH2:5]1

Participants

6

Reactant 5

HCID 923Sodium ionHCID 6228DimethylformamideHCID 166653HydrideHCID 27348452-(Pyrrolidin-1-yl)phenolHCID 15544598tert-butyl N-(5-chloro-2-nitrophenyl)-N-methylcarbamate

Product 1

HCID 18461415t-butyl N-[2-nitro-5-(2-pyrrolidinophenoxy)phenyl]-N-methylcarbamate

Sources & evidence

ORD record
ord-84a38f7c3f374b6e9ce5d8e8dac85554
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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