Bis(eta-cyclopentadienyl) iron → HCID 178460956, compound

HRID 962954Notes

Reaction equation

HRID 962954 reaction equation
[CH-:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:6]1[CH:10]=[CH:9][CH:8]=[CH:7]1.[Fe+2:11].[CH2:12]([SiH:15]([C:17]([CH3:20])([CH3:19])[CH3:18])[Cl:16])[CH:13]=[CH2:14]>>[Cl:16][SiH:15]([C:17]([CH3:20])([CH3:19])[CH3:18])[CH2:12][CH:13]([C-:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1)[CH3:14].[CH-:6]1[CH:10]=[CH:9][CH:8]=[CH:7]1.[Fe+2:11]

Participants

3

Reactant 2

HCID 7611Bis(eta-cyclopentadienyl) ironHCID 123221190HCID 123221190, compound

Product 1

HCID 178460956HCID 178460956, compoundYield 26%

Procedure

In the same apparatus and procedures as EXAMPLE 1, 0.60 g (3.22 mmol) of ferrocene was reacted with 1.05 g (6.44 mmol) of allyl-tert-butylchlorosilane under dry nitrogen atmospheric pressure for 2 hrs. After the addition of the catalyst solution, the reaction mixture was stirred for 2 hrs to complete the alkylation. The solvent was distilled off at atmospheric pressure and the products were then extracted with 20.0 ml of hexane. Vacuum distillation of the reaction products at 200° C. and at 0.5 torr produced (3-chloro-1,4,4-trimethyl-3-silapentyl)ferrocene [yield: 26% (based on the reacted ferrocene)].

Workup

  1. additionAfter the addition of the catalyst solution
  2. distillationThe solvent was distilled off at atmospheric pressure
  3. extractionthe products were then extracted with 20.0 ml of hexane
  4. distillationVacuum distillation of the reaction products at 200° C.

Sources & evidence

ORD record
ord-299057defacc4edd82537cb7c3c4543c
Source dataset
uspto-grants-1998_06
Patent number
US05760263

Reaction notes

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