Formic Acid → HCID 131720703, compound

HRID 963574Notes

Reaction equation

HRID 963574 reaction equation
[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[CH2:7][CH2:8][O:9][CH2:10][CH2:11][S:12][CH2:13][CH2:14]C1OCCO1.[CH:20](O)=[O:21]>>[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[CH2:7][CH2:8][O:9][CH2:10][CH2:11][S:12][CH:13]([CH3:14])[CH:20]=[O:21]

Participants

3

Reactant 2

HCID 284Formic AcidHCID 19082314HCID 19082314, compound

Product 1

HCID 131720703HCID 131720703, compound

Procedure

The material from step b) (0.850 g) was dissolved in 80% formic acid (10 ml) and left to stand at room temperature for 22 hours. The mixture was partitioned between ether and water. The layers were separated and the aqueous layer extracted with ether. The ethereal extracts were combined, washed with brine, dried (MgSO4) and evaporated is under reduced pressure to yield the subtitled compound as an oil (0.70 g).

Workup

  1. waitleft
  2. customThe mixture was partitioned between ether and water
  3. customThe layers were separated
  4. extractionthe aqueous layer extracted with ether
  5. washwashed with brine
  6. dry with materialdried (MgSO4)
  7. customevaporated

Sources & evidence

ORD record
ord-67c654a460a848d1a89e746080f413aa
Source dataset
uspto-grants-1998_06
Patent number
US05763465

Reaction notes

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