Palladium Chloride → Palladium triflate

HRID 964709Notes

Reaction equation

HRID 964709 reaction equation
Cl[Pd:2]Cl.[OH:4][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:7])=[O:6]>C(Cl)Cl>[O-:7][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:6])=[O:4].[Pd+2:2].[O-:7][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:6])=[O:4]

Participants

4

Reactant 2

HCID 24290Palladium ChlorideHCID 62406Trifluoromethanesulfonic acid

Product 1

HCID 11603820Palladium triflate

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

PdCl2 (1.0 g, 5.6 mmol) was slurried in CH2Cl2 (20 mL) and triflic acid (1.7 g, 11.3 mmol) was added dropwise. The mixture was stirred at room temperature overnight. The solvent was removed and 0.9 g of rust color solid was collected. 19F NMR (CDCl3): δ-78.5.

Workup

  1. customThe solvent was removed
  2. custom0.9 g of rust color solid was collected

Sources & evidence

ORD record
ord-0c79103282e745e19f28a3bfb8cac528
Source dataset
uspto-grants-1998_06
Patent number
US05770678

Reaction notes

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