HuagongsheHuagongshe Chemistry Print Report · For research reference only
Silicon tetrachloride → HCID 131719478, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Silicon tetrachloride | HCID 24816 | — |
| Reactant | Trifluoromethanesulfonic acid | HCID 62406 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 131719478 | HCID 131719478 | — |
Reaction Steps
SiCl4 (3 g, 17.6 mmol) was dissolved in CH2Cl2 (75 mL) and triflic acid (10.6 g, 70.7 mmol) was added dropwise. The mixture was stirred at room temperature over the weekend. The solvent was removed and 4.8 g of brown liquid was collected. 19F NMR (DMSO-d6): δ-76.4 (intense), small broad peaks at -77.8 and -77.95.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05770678 |
| Source dataset | uspto-grants-1998_06 |
| ORD ID | ord-397028b820544a8cad67d28070e45228 |
| Source note | uspto-grants-1998_06 |