Dimethyl Sulfate → HCID 69592045, compound

HRID 965860Notes

Reaction equation

HRID 965860 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([CH:9]=[CH:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][N+:12]=2[O-])[CH:5]=[CH:6][C:7]=1[Cl:8].COS(OC)(=O)=O.[C-:25]#[N:26].[Na+]>CCCCCC>[Cl:1][C:2]1[CH:3]=[C:4]([CH:9]=[CH:10][C:11]2[N:12]=[C:13]([C:25]#[N:26])[CH:14]=[CH:15][CH:16]=2)[CH:5]=[CH:6][C:7]=1[Cl:8]

Participants

5

Reactant 3

HCID 6497Dimethyl SulfateHCID 8929Sodium CyanideHCID 69592076HCID 69592076, compound

Product 1

HCID 69592045HCID 69592045, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

Following the general method described in example 2b, 2-[2-(3,4-dichloro-phenyl)-vinyl]-pyridine 1-oxide was reacted first with dimethylsulfate and then with NaCN. After extraction and crystallization the title compound was obtained as a white crystalline material. Mp. 124-125° C. (hexane), MS: m/e=274 (M+).

Workup

  1. extractionAfter extraction and crystallization the title compound
  2. customwas obtained as a white crystalline material

Sources & evidence

ORD record
ord-3b35021f2ac047e8abd9ccbc02e81132
Source dataset
uspto-grants-2005_10
Patent number
US06951875B2

Reaction notes

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