1,3-Dibromopropane → 3-(4-Bromo-phenyl)-6-(3-bromo-propoxy)-benzo[b]thiophene

HRID 966296Notes

Reaction equation

HRID 966296 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[C:9]3[CH:16]=[CH:15][C:14]([OH:17])=[CH:13][C:10]=3[S:11][CH:12]=2)=[CH:4][CH:3]=1.[Br:18][CH2:19][CH2:20][CH2:21]Br>>[Br:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[C:9]3[CH:16]=[CH:15][C:14]([O:17][CH2:21][CH2:20][CH2:19][Br:18])=[CH:13][C:10]=3[S:11][CH:12]=2)=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 80011,3-DibromopropaneHCID 179328883-(4-Bromo-phenyl)-benzo[b]thiophen-6-ol

Product 1

HCID 223139683-(4-Bromo-phenyl)-6-(3-bromo-propoxy)-benzo[b]thiophene

Procedure

In analogy to example 27.1, 3-(4-Bromo-phenyl)-benzo[b]thiophen-6-ol and 1,3-dibromopropane were converted to yield 3-(4-Bromo-phenyl)-6-(3-bromo-propoxy)-benzo[b]thiophene, MS: 424 (M, 2Br).

Sources & evidence

ORD record
ord-46b1cb06c1f547d5bfcbbd797cd1cbbc
Source dataset
uspto-grants-2005_10
Patent number
US06951879B2

Reaction notes

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