N-Methylallylamine → Allyl-(1-ethynyl-cyclopentyl)-methyl-amine

HRID 966345Notes

Reaction equation

[C:1]([C:3]1(O)[CH2:7][CH2:6][CH2:5][CH2:4]1)#[CH:2].[CH3:9][NH:10][CH2:11][CH:12]=[CH2:13]>>[CH2:11]([N:10]([C:3]1([C:1]#[CH:2])[CH2:7][CH2:6][CH2:5][CH2:4]1)[CH3:9])[CH:12]=[CH2:13]

Participants

Reactant 2

HCID 69391N-Methylallylamine

HCID 870741-Ethynylcyclopentanol

Product 1

HCID 22313997Allyl-(1-ethynyl-cyclopentyl)-methyl-amine

Procedure

In analogy to example 37.5 and 37.6, 1-Ethinylcyclopentanol and N-Methyl-allylamine were converted to yield Allyl-(1-ethynyl-cyclopentyl)-methyl-amine as colorless oil, MS: 163 (M).

Sources & evidence

ORD record: ord-794a09e5ba174ecfaac0beea3a91ca5e
Source dataset: uspto-grants-2005_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06951879B2

Reaction notes

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