HuagongsheHuagongshe Chemistry Print Report · For research reference only
Isobutyraldehyde → HCID 12045652, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Isobutyraldehyde | HCID 6561 | — |
| Reactant | Benzenesulfonic acid, 4-methyl-, compd. with pyridine (1:1) | HCID 466102 | — |
| Reactant | N,O-Dibenzylhydroxylamine | HCID 11063773 | — |
| Solvent | MeOH tetrahydrofuran | HCID 21899815 | — |
| Product | HCID 12045652 | HCID 12045652 | — |
Reaction Steps
To a solution of II (1 eq.), 2-methylpropanal (1 eq.) and BH3(pyridine) (1 eq.) in THF:MeOH (1:3) was added PPTS (1 eq.). The reaction mixture was stirred at rt for 12 h and afforded, after aqueous workup and purification by column chromatography, III as a colorless oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06951958B1 |
| Source dataset | uspto-grants-2005_10 |
| ORD ID | ord-0f37980ba90743f494180b45d7b29105 |
| Source note | uspto-grants-2005_10 |