HuagongsheHuagongshe Chemistry Print Report · For research reference only
DMSO triethylamine → HCID 178484046, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | DMSO triethylamine | HCID 86583882 | — |
| Reactant | HCID 178484047 | HCID 178484047 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 178484046 | HCID 178484046 | 97.7% |
Reaction Steps
In analogy to the method described in example 1.2, 1.65 g (5.66 mmol) of trans-(4-hydroxymethyl-cyclohexylmethyl)-methyl-carbamic acid benzyl ester were treated with dimethylsulfoxide/triethylamine in dichloromethane between −78° C. and room temperature to yield 1.6 g (97.6%) trans-(4-formyl-cyclohexylmethyl)-methyl-carbamic acid benzyl ester as colorless oil, MS: 289 (M).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06953806B2 |
| Source dataset | uspto-grants-2005_10 |
| ORD ID | ord-e9aad78975db4fd997fcbadf146dc235 |
| Source note | uspto-grants-2005_10 |