HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Bromobenzaldehyde → Methyl 2-[2-(4-bromophenyl)ethenyl]-6-chlorobenzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Bromobenzaldehyde | HCID 70741 | — |
| Reactant | 1,5-Diazabicyclo(4.3.0)non-5-ene | HCID 76349 | — |
| Reactant | HCID 86594264 | HCID 86594264 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | Methyl 2-[2-(4-bromophenyl)ethenyl]-6-chlorobenzoate | HCID 69410701 | — |
Reaction Steps
To a mixture of. 44.6 g (84.9 mmol) of 3-chloro-2-methoxycarbonylbenzyltriphenylphosphonium bromide and 16.7 g (90.4 mmol) of 4-bromobenzaldehyde was added 150 ml of acetonitrile, and then, 14.8 g (119 mmol) of 1,5-diazabicyclo[4,3,0]-5-nonene was added dropwise to the mixture. Thereafter, the mixture was refluxed for 3 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07309718B2 |
| Source dataset | uspto-grants-2007_12 |
| ORD ID | ord-0b0642579b3745d587fec8dc9cb3d9a9 |
| Source note | uspto-grants-2007_12 |