huagongshe.com
HRID970294

反应详情

EQUATION

反应方程式

HRID 970294 的结构方程式

REACTANTS

反应物

2
结构：CCN1CCN(C(=O)N[C@@H](C(=O)N[C@@H]2C(=O)N3[C@@H]2SC(C)(C)[C@@H]3C(=O)O)c2ccccc2)C(=O)C1=O
HCID43672

Piperacillin

C23H27N5O7S

结构：CCCCCCCCCCC(N[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1NC(C)=O)C(N)=O
HCID131726725

未命名化合物

PRODUCTS

生成物

1
结构：CCCCCCCCCCC(N[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1NC(C)=O)C(N)=O.CCN1CCN(C(=O)N[C@@H](C(=O)N[C@@H]2C(=O)N3[C@@H]2SC(C)(C)[C@@H]3C(=O)O)c2ccccc2)C(=O)C1=O
HCID131726724

未命名化合物

收率 97%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC(=O)O
溶剂HCID176

Acetic Acid

C2H4O2

PROCEDURE

实验过程

Piperacillin (2.00 g, 3.87 mmol) and 2-acetamido-2-deoxy-N-(1-amino-(R/S)-dodecoyl)-β-D-glucopyranosylamine (32) (1.61 g, 3.87 mmol) were dissolved in 95% acetic acid. Once fully dissolved, the solution was filtered and lyophilised to give (35) as a white solid (3.50 g, 97%).

WORKUP

后处理

  1. dissolutionOnce fully dissolved
  2. filtrationthe solution was filtered