HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → Dimethyl 4-[3-(4-methoxymethoxy-3-methylphenyl)propyl]phthalate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 9-Borabicyclo(3.3.1)nonane | HCID 78966 | — |
| Reactant | 1-(Ethoxymethoxy)-2-methyl-4-(prop-2-en-1-yl)benzene | HCID 17983071 | — |
| Reactant | 1,2-Dimethyl 4-(trifluoromethanesulfonyloxy)benzene-1,2-dicarboxylate | HCID 19089344 | — |
| Catalyst | HCID 178527691 | HCID 178527691 | — |
| Product | Dimethyl 4-[3-(4-methoxymethoxy-3-methylphenyl)propyl]phthalate | HCID 17983092 | — |
Reaction Steps
In a manner similar to Example 1e, by reacting 4.5 g (21.6 mmol) of 4-allyl-1-ethoxymethoxy-2-methylbenzene with 6.3 g (25.7 mmol) of 9-BBN, 7.4 g (21.6 mmol) of dimethyl 4-trifluoromethanesulphonyloxyphthalate, 5.9 g (42.6 mmol) of potassium carbonate and 880 mg (1.05 mmol) of dichloropalladium diphosphinoferrocene. A yellow oil is obtained (m=7 g, y=80%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07312249B2 |
| Source dataset | uspto-grants-2007_12 |
| ORD ID | ord-b9bccb856f354f35866e50b586285436 |
| Source note | uspto-grants-2007_12 |